So you want to add an alias to a user synced to O365? Fat chance. Since it is synced you cannot adjust the user attributes including adding an alias. You have to remove dirsync or adjust the attribute in ADSIEdit and wait for it to sync. Not the best method.
Set-MsolDirSyncEnabled -EnableDirSync $false
To verify:
(Get-MSOLCompanyInformation).DirectorySynchronizationEnabled
Proxy Address through ADSIEdit:
Set-MsolDirSyncEnabled -EnableDirSync $false
To verify:
(Get-MSOLCompanyInformation).DirectorySynchronizationEnabled
Proxy Address through ADSIEdit:
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